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Zeta Potential Analyzer

Nanoparticles or colloidal particles in solution usually acquire a charge due to the adsorption of surface functional groups or ions, forming a layer of ions around the particles.Electric Double LayerThe electric double layer can be divided into the one close to the particle surface.Stern Layerwith the outsideDiffuse Layer

 

Within the diffuse layer there exists a hypothetical interface known as the Slipping PlaneThe position represents the boundary of relative motion between the particles in the solution and the surrounding liquid, and the potential on this plane is defined asZeta PotentialThe ions located inside the sliding plane move along with the particles, so the Zeta potential can reflect the particles in the solution.Actual surface electrical properties and dispersion behavior

 

Zeta potential is influenced by various factors, including the particles'Surface chemical properties, solution pH value, types and concentrations of electrolytesTherefore, it is often used to evaluate colloidal systems or nanomaterials.Important indicators of dispersion stabilityGenerally speaking, the greater the absolute value of the Zeta potential, the stronger the electrostatic repulsive force between particles, and the higher the dispersion and stability of the system.

 

During the measurement process, the Zeta potential analyzer will apply to the sample.external electric fieldto generate charged particles in solutionElectrophoresis,the instrument usesLaser Doppler Velocimetry, LDVMeasure the particle's movement speed and calculate itsElectrophoretic Mobility,Finally, the electrophoretic mobility is converted using Henry's Equation.Zeta potential value

Technical Features
Complementary to particle size analysis
Zeta potential is often used in conjunction with DLS particle size analysis, allowing for a simultaneous understanding of particle size and surface charge, providing more comprehensive information on the dispersion state of nanomaterials.
Quick measurement and easy operation
The measurement process is quick and requires a small amount of samples, making it suitable for material research, process monitoring, and quality control analysis needs.
Analyze the impact of the solution environment on particle behavior.
It is possible to study the effects of different pH values, electrolyte concentrations, or types of ions on the surface potential and dispersibility of particles, assisting in the optimization of material formulations and dispersion conditions.
Applicable to various material systems
Surface electrical property analysis applicable to different material systems such as nanomaterials, metal oxides, polymer emulsions, colloidal solutions, biomolecules, and drug nanocarriers.
Evaluate the stability of colloidal and nano-dispersion systems
Through the magnitude and polarity of the Zeta potential, the strength of the electrostatic repulsive force between particles can be determined, and thus the tendency of particles to aggregate or settle can be assessed.
High sensitivity surface electrical property measurement
Zeta potential analysis can accurately measure the surface charge characteristics of nanoparticles and colloidal systems, obtaining stable measurement results even under low concentration sample conditions.
Zeta potential and dispersion stability relationship
Zeta potential (mV) dispersion stability
0 ~ ±10 Very unstable, prone to aggregation
±10 ~ ±30 lower stability
±30 ~ ±60 Dispersion stability
> ±60 highly stable
Analysis of Zeta potential changes under different pH conditions

Analysis results

This figure shows the variation of Zeta potential of the sample in different pH environments. The horizontal axis represents pH values, while the vertical axis represents Zeta potential (mV).

 

Under low pH (acidic) conditionsAt low pH, Zeta potential is near 0 mV, indicating weak electrostatic repulsion and potential aggregation.
As the pH value increasesZeta potential gradually becomes negative, indicating that the particle surface carries a negative charge.
Under high pH (alkaline) conditionsAt high pH (alkaline), the absolute value of Zeta potential increases (around -30 mV), enhancing repulsion and improving dispersion stability.

This result showsSolution pH affects particle surface charge and dispersion stability.

Types of machines

Malvern Nano-ZS

Malvern Nano-ZS is a system that combinesDynamic Light Scattering (DLS) and Zeta potential analysishigh-precision particle analyzer, which can be used to measure particles from nanometers to micrometers.size distribution, dispersion state, and surface charge

This instrument uses the principle of laser light scattering to measure the particles in the solution.Brownian motionThe particle's calculation through the variation of scattered light intensity.Hydrodynamic DiameterAt the same time, it can be accessed throughElectrophoretic Light Scattering (ELS)The technology measures the movement speed of particles in an electric field, and then calculates theirZeta potentialto evaluate the dispersion stability of particles.

Nano-ZS hasHigh sensitivity and high resolutionIt can quickly analyze nanomaterials, colloidal systems, biomolecules, and various types of dispersions, making it a commonly used analytical instrument in material research, nanotechnology, biomedical, and chemical industries.

Contact
Contact Window
Taiwan Laboratory

Mr. Zhong

Ext. +886-3-6116678 ext:3275

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